High-resolution zero-kinetic-energy pulsed field ionization photoelectron spectra of the Na„H2O... complex

Selective field ionization of high Rydberg states: Application to zero-kinetic-energy photoelectron spectroscopy

Sequences of pulsed electric fields have been designed and tested that enable a higher selectivity in the pulsed field ionization of high Rydberg states (n>100) than has so far been possible. The enhanced selectivity originates from the permutation of the parabolic quantum numbers n1 and n2 that is induced by a sufficiently rapid inversion of the electric field polarity during a pulse sequence....

Rotationally resolved photoelectron spectra in resonance enhanced multiphoton ionization of HCl via the F 12 Rydberg state

Articles you may be interested in Dynamics of high‐n Rydberg states employed in zero kinetic energy‐pulsed field ionization spectroscopy via the F 1Δ2, D 1Π1, and f 3Δ2 Rydberg states of HCl Resonance enhanced multiphoton ionization photoelectron spectroscopy and pulsed field ionization via the F 1Δ2(v'=0) and f 3Δ2(v'=0) Rydberg states of HCl

High resolution study of low-lying correlation satellites below 25 eV in xenon probed by pulsed-field-ionization-zero-kinetic- energy photoelectron spectroscopy

ZEKE - PFI spectroscopy of 1 : 1 complexes of sodium with water and ammonia

ZEKE-PFI (zero kinetic energy pulsed field ionization) photoelectron spectra of the Na(H 20), Na(D20), Na(NH 3), and Na(ND3) complexes are reported. Spectra of all four complexes were obtained by single-photon ionization, and, for the Na(NH 3) and Na(ND3) complexes, by two-color (I+ I') photoionization as well, with the A E state serving as the intermediate resonance. Improved values for the io...

Zero kinetic energy-pulsed field ionization and resonance enhanced multiphoton ionization photoelectron spectroscopy: Ionization dynamics of Rydberg states in HBr

The results of rotationally resolved resonance enhanced multiphoton ionization photoelectron spectroscopy and zero kinetic energy-pulsed field ionization studies on HBr via various rotational levels of the F D2 and f D2 Rydberg states are reported. These studies lead to an accurate determination of the lowest ionization threshold as 94 098.961 cm. Observed rotational and spin–orbit branching ra...